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Transition Metal Halide Salts and Complexes of 2-Aminopyrimidine: Cobalt(II) and Nickel(II) compounds, Crystal Structures of Bis(2-Aminopyrimidinium)MX 4 [M = Co, Ni; X = Cl, Br] and 2-Aminopyrimidinium(+2) [NiBr 2 (H 2 O) 4 ]Br 2

✍ Scribed by Masaki, Miyuki Eiraku; Prince, Barry J.; Turnbull, Mark M.


Book ID
120003547
Publisher
Taylor and Francis Group
Year
2002
Tongue
English
Weight
257 KB
Volume
55
Category
Article
ISSN
0095-8972

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One-dimensional structures of nickel(II)
✍ M John Plater; Mark R.St J Foreman; Thomas Gelbrich; Michael B Hursthouse πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 English βš– 133 KB

Treatment of 1,3-bis(4-pyridyl)propane with Co(II)(ClO 4 ) 2 or Ni(II)(ClO 4 ) 2 gives isostructural one-dimensional coordination polymers. The metal ions have an octahedral geometry and are bridged by two crystallographically independent ligands along each chain. Alongside each coordination chain a