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Transition-Metal-Free Synthesis of Fluorinated Arenes from Perfluorinated Arenes Coupled with Grignard Reagents

โœ Scribed by Sun, Yunqiang; Sun, Hongjian; Jia, Jiong; Du, Aiqin; Li, Xiaoyan

Book ID
121530804
Publisher
American Chemical Society
Year
2014
Tongue
English
Weight
324 KB
Volume
33
Category
Article
ISSN
0276-7333

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โœ John E. Mc Murry; Subramaniam Mohanraj ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 185 KB

Aryl triflates react with higher order nixed cuprates R2Cu(CN)Li2 to produce arenes in good yield. The aryl ring nay have either an electron-donating or an electron-withdrawing substituknt; the organocuprate may be either primary, aryl, or vinyl. We reported 1,2 recently a new method of regiospecif