✦ LIBER ✦

Transition metal dienyls in organic synthesis: A convenient preparation of σ-bonded tin and zirconium dienyls

✍ Scribed by Michael D Fryzuk; Gordon S Bates; Charles Stone

Book ID: 104218389
Publisher: Elsevier Science
Year: 1986
Tongue: French
Weight: 188 KB
Volume: 27
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)84306-3

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✦ Synopsis

Chemoselective hydrozirconation

of 1-ene-3-yne molecules using (nS-CgHg)ZZrHC1, 1 represents the first general synthesis of zirconium dienyls, which, via transmetallation, can be stereoselectively transformed into synthetically useful tin dienyl derivatives.

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