Transition metal coordination polymers: Synthesis and catalytic study for hydroxylation of phenol and benzene
β Scribed by Hanna S. Abbo; Salam J.J. Titinchi
- Book ID
- 116231813
- Publisher
- Elsevier Science
- Year
- 2012
- Tongue
- English
- Weight
- 664 KB
- Volume
- 435-436
- Category
- Article
- ISSN
- 0926-860X
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## Abstract The reaction of nickel thiocyanate with pyrazine in a 1:2 ratio leads to the new ligandβrich 1:2 (ratio metal/ligand) compound [Ni(SCN)~2~(pyrazine)~2~]__~n~__ (1), in which the metal atoms are coordinated by four N atoms of pyrazine ligands and two N atoms of thiocyanate anions in a sl
A series of Fe-MCM41s with different iron content have been synthesized and characterized by XRD, BET, HRTEM, FT-IR, UV-vis and ICP techniques. Their catalytic performances for the direct hydroxylation of phenol were also studied. Results indicated that the mesoporous structure did not collapse unti