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Transition metal complexes with the thiosemicarbazide-based ligands—I. Nickel(II) complexes with the quadridentate ligands based on S-methylisothiosemicarbazide; X-ray crystal structure of (acetyl-acetone N(1)-salicylidene-S-methylizothiosemicarbazonato) nickel(II)

✍ Scribed by Vukadin M. Leovac; Vladimir Divjaković; Valerija I. Češljević; Peter Engel


Book ID
108428270
Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
615 KB
Volume
6
Category
Article
ISSN
0277-5387

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Synthesis and X-ray Crystal Structure of
✍ Berkessel, Albrecht ;Bolte, Michael ;Neumann, Thomas ;Seidel, Lutz 📂 Article 📅 1996 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 818 KB

The six-step synthesis of a chiral, pentadentate dihydrosalen ligand, carrying a mercaptomethyl group as additional binding site, is described. When this ligand was treated with nickel(I1) salts, a planar tetracoordinated nickel chelate was obtained, and not the expected pentacoordinated species. Th