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Transition-Metal Complexes with Sulfur Ligands. 132. 1 Electron-Rich Fe and Ru Complexes with [MN 2 S 3 ] Cores Containing the New Pentadentate Ligand ‘N 2 H 2 S 3 ‘ 2- (= 2,2‘-Bis(2-mercaptophenylamino)diethyl Sulfide(2−))

✍ Scribed by Sellmann, Dieter; Utz, Jürgen; Heinemann, Frank W.


Book ID
126405351
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
211 KB
Volume
38
Category
Article
ISSN
0020-1669

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Electron-Rich Fe and Ru Complexes with t
✍ Dieter Sellmann; Jürgen Utz; Frank W. Heinemann 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 216 KB 👁 1 views

N ligands / S ligands / Iron / Ruthenium / Pentadentate ligands In order to obtain iron and ruthenium complexes which are [Ru(PPh 3 )(ЈN 3 H 3 S 2 Ј-Me 2 )]I 2 (8) proved as inert towards substitution as 7. Complex 8 could reversibly be analogous to [M(L)(ЈNHS 4 Ј)] and [M(L)(ЈN 2 H 2 S 3 Ј)] comple