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Transition metal complexes-catalyzed synthesis of 2,4,7,9-tetraoxadecane and homologs

✍ Scribed by M.A. Fontaine; H. Piette; A.F. Noels; M. Beaujean; C. Detry

Book ID: 104259160
Publisher: Elsevier Science
Year: 1998
Tongue: French
Weight: 195 KB
Volume: 39
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(98)00507-3

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✦ Synopsis

polyether molecules are readily available from cheap acetals with a catalyst system based on rutheniarn and tin(I1) chloride. As a model reaction 1,3-dioxolane 2 reacts with dimethoxymethane 3 to yield 78% of 2,4,7,9-tetraoxadecane l.

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