Transition metal complex catalyzed carbonylation of organic halides in the presence of molecular sieves instead of base
β Scribed by Hisao Urata; Nan-Xin Hu; Hisayuki Maekawa; Takamasa Fuchikami
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- French
- Weight
- 281 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0040-4039
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swurion me L ~L U J ~ rnar suoiimes auring rne reaction. in this way 1.4g (6.4mmol) of sublimed Cr(C0)6 and 1.8g (12.1 mmol) of ( I ) in lOml of dioxane were heated for about 36 h at the b. p. The unconsumed Cr(C0)6 was then removed from the cooled yellowish-brown solution by filtration, the dioxane
## Abstract The transition metalβcatalyzed ringβopening polymerization of dimethyl[1]silaferrocenophane (fcSiMe~2~) (1), fcβ=βFe(__Ξ·__βC~5~H~4~)~2~), in the presence of MePhSiH~2~, or the chlorosilanes ClMe~2~SiH, ClMePhSiH, or ClPh~2~SiH has been shown to allow access to poly(ferrocenylsilane)s R^