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Transition-metal-catalyzed reactions of diazo compounds. 2. Addition to aromatic molecules: catalysis of Buchner's synthesis of cycloheptatrienes

โœ Scribed by Anciaux, A. J.; Demonceau, A.; Noels, A. F.; Hubert, A. J.; Warin, R.; Teyssie, P.


Book ID
126144994
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
566 KB
Volume
46
Category
Article
ISSN
0022-3263

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The stereochemical course of Ni-and Pd-catalyzed reactions of t+)(S)-1 with isobutylmetal reagents has been elucidated by preparing the allene (+)-2 via an anti stereoselective transformation of the propargylic acetate c+)(R)-4 with organocuprates.