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Transition-Metal-Catalyzed Carbenoid Reactions of Sulfonium Ylides

✍ Scribed by Paul Müller; Daniel Fernandez; Patrice Nury; Jean-Claude Rossier

Publisher
John Wiley and Sons
Year
1999
Tongue
German
Weight
135 KB
Volume
82
Category
Article
ISSN
0018-019X

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✍ Paul Müller; Daniel Fernandez; Patrice Nury; Jean-Claude Rossier 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 291 KB 👁 1 views

Transition metal-catalyzed decomposition of phenyliodonium and diphenylsulfonium ylides was investigated with regard to application in asymmetric carbenoid reactions. Phenyliodonium ylides react in the presence of Rh(II) catalysts with the same selectivity in inter-and intramolecular cyclopropanatio