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Transient resonance Raman spectra and vibrational assignments of the S1 state of trans-stilbene and its deuterated analogues

โœ Scribed by Hiro-o Hamaguchi; Taeko Urano; Mitsuo Tasumi

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
316 KB
Volume
106
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

Raman spectra of St tnns-stilbcnc

and its deutcrotcd nnalogucs were obscrvcd. Assignments of the three olcfinic vihrations have been made on the basis of the isotopic Crcquency shifts. The St Raman spectrn arc intcrpretcd according to the newly cstablishcd vibrational assignments, which arc different from those proposed previously.

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Observation of transient resonance raman
Observation of transient resonance raman spectra of the S1 state of trans-stilbene
โœ Hiro-o Hamaguchi; Chihiro Kato; Mitsuo Tasumi ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 379 KB

Transient resonance Raman spectra of transstilbene in n-hexane have been obtained using two pulsed lasers at 266 and 585 nm. The former was used to pump the molecule to the fust excited singlet state (Sr) and the latter to proble spontaneous Raman scattering in resonance with the S, + Sr electronic

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## Transient absorpkn and Raman spectra OC the S, stale of biphenyl in solution were ohserved. The caLion radical or biphenyl. which was probably formed by n srcpw.isr IWO-pbo~on rxcimIion m 766 nm. was also drlected. The vibra~ionzl rrequcncics or the S, stakand Ihe cation radical are compared wi