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Transient Raman evidence of the one-way cis to trans isomerization in the lowest excited triplet state of 2-styrylanthracene

✍ Scribed by Hamaguchi, Hiroo.; Tasumi, Mitsuo.; Karatsu, Takashi.; Arai, Tatsuo.; Tokumaru, Katsumi.


Book ID
127190384
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
301 KB
Volume
108
Category
Article
ISSN
0002-7863

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## Abstract The possibility of population of the lowest‐lying triplet state (__T__~1~) in the early events of the photochemical isomerization process of a model chromophore of Rhodopsin (Rh) has been analyzed using multireference perturbation theory (CASPT2//CASSCF) methods. It is shown that the ch