Transient Palladadiphosphanylcarbenes: Singlet Carbenes with an “Inverse” Electronic Configuration (p π2 instead of σ 2 ) and Unusual Transannular Metal−Carbene Interactions (π C→Pd Donation and σ Pd→C Back-donation)

✍ Scribed by Vignolle, Joan; Gornitzka, Heinz; Maron, Laurent; Schoeller, Wolfgang W.; Bourissou, Didier; Bertrand, Guy

• Book ID: 120846732
• Publisher: American Chemical Society
• Year: 2007
• Tongue: English
• Weight: 248 KB
• Volume: 129
• Category: Article
• ISSN: 0002-7863
• DOI: 10.1021/ja066738j