𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Transient decay studies of photophysical processes in aromatic polymers. VI. Intramolecular excimer formation and dissociation in polystyrene and styrene–methyl methacrylate copolymers

✍ Scribed by Soutar, I. ;Phillips, D. ;Roberts, A. J. ;Rumbles, G.

Publisher
Wiley (John Wiley & Sons)
Year
1982
Tongue
English
Weight
634 KB
Volume
20
Category
Article
ISSN
0098-1273

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The time‐resolved fluorescence behavior of polystyrene and a series of styrene–methyl methacrylate copolymers has been examined by using pulsed laser excitation. Although the photophysical characteristics of styrene‐ and naphthalene‐containing polymers may be described by the same general kinetic scheme, some differences in the nature of the photophysical interactions are apparent. Umambiguous evidence for the occurrence of excimer dissociation into excited‐state monomer in polymers incorporating styrene chromophores is presented.

📜 SIMILAR VOLUMES

Transient decay studies of photophysical
Transient decay studies of photophysical processes in aromatic polymers. V. Temperature dependence of excimer formation and dissociation in copolymers of 1-vinylnaphthalene and methyl methacrylate
✍ Phillips, D. ;Roberts, A. J. ;Soutar, I. 📂 Article 📅 1982 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 468 KB

## Abstract The use of pulsed laser excitation upon a series of 1‐vinylnaphthalene/methyl methacrylate co‐polymers in which the intramolecular chromophore concentration is varied over a wide composition range has allowed the individual rate constants governing intramolecular excimer formation to be

Transient decay studies of photophysical
Transient decay studies of photophysical processes in aromatic polymers—III. Concentration dependence of excimer formation in copolymers of acenaphthylene and methyl methacrylate
✍ D. Phillips; A.J. Roberts; I. Soutar 📂 Article 📅 1981 🏛 Elsevier Science 🌐 English ⚖ 467 KB

The fluorescence behaviour of a series of acenaphthylene/methyl methacrylate copolymers covering a wide range of intramolecular chromophore compositions has been examined using pulsed laser excitation. The decay of emission intensity in the region of monomer fluorescence could be described only by t