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Transient Amino-Hydrazino-Carbenes: A Radical Pathway for Intramolecular 1,2-Migration Reactions

✍ Scribed by Xavier Cattoën; Heinz Gornitzka; Fook S. Tham; Karinne Miqueu; Didier Bourissou; Guy Bertrand

Book ID: 102172461
Publisher: John Wiley and Sons
Year: 2007
Tongue: English
Weight: 170 KB
Volume: 2007
Category: Article
ISSN: 1434-193X
DOI: 10.1002/ejoc.200600901

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✦ Synopsis

Abstract

The transient amino‐hydrazino‐carbenes 2c–e are reported to undergo intramolecular 1,2‐migration reactions that proceed through a radical pathway according to DFT calculations. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

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