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Transient absorption spectra of the excited states of triptycene and 3-acetyltriptycene

✍ Scribed by Tadashi Sugawara; Hiizu Iwamura; Nobuaki Nakashima; Keitaro Yoshihara; Hisaharu Hayashi

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
344 KB
Volume
101
Category
Article
ISSN
0009-2614

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✦ Synopsis

The S,l + S, absorption (Ama is 650 nm, E > 7 X lo3 hi-' cm-') of triptycene and the Tn +T, absorptions ($na.. is 370 and 550 nm) of 3-acetyltriptycene have been determined by nanosecond hser spectroscopy_ A small contribution of charge-transfer character and subsequent reactivity in the excited states are discussed.

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