## AbsWact-Flurorescence spectra of a number of aromatic hydrocarbons, their excimers and exciplexes with diethylaniline have been measured in n-hexane under aerobic conditions. It has been found that the value of the red shift of the structureless excimer or exciplex band in reference to the mono
Transformation of the excitation energy in excimers and exciplexes of aromatic hydrocarbons
β Scribed by N. L. Vekshin
- Publisher
- Springer US
- Year
- 1991
- Tongue
- English
- Weight
- 508 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0021-9037
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π SIMILAR VOLUMES
The triplet lifetime of aromatic hydrocarbons in liquid solution is relativc:jr short compared with the lifetime in a rigid solution. Until now this difference has been exphined by an impurity quenching mechanism. An alternative explanation is given, assuming quenching of a triplet molecule by B sin
The emission resulting from the reaction of electrogenerated radical anions (A> and cations (Dt> (ECL) for four systems which provide evidence for the intermediacy of excimers or exciplexes is described. The effect of solvent and supporting electrolyte concentration and the energetics of the radical
## Abstract Fluorescence rise and decay processes were measured and rate parameters were determined for the pyreneβtriβ__n__βbutylamine and pyreneβN,Nβdiethylaniline exciplex system in various solvents. An additional activation energy over that for the diffusional motion appears necessary for both