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Transfer technology III: The synthesis of bridged cyclic polyenes using a new retrosynthetic algorithm as a guide.

✍ Scribed by R.N. Warrener; J-M. Wang; K.D.V. Weerasuria; R.A. Russell


Book ID
104228538
Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
300 KB
Volume
31
Category
Article
ISSN
0040-4039

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✦ Synopsis


This route to bridged [4] and [8] annulenes employs a new retrosynthetic algorithm, transannular xbond pairing, as its basis and improved transfer reagents for substituted cyclobutadienes to achieve the synthesis.

In an earlier report2 we demonstrated the use of transfer technology in organic synthesis. This technique uses