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Transannular oxidation of bis-arylhydrazones of cyclodecan-1,6-dione

โœ Scribed by Elizabeth Malamidou-Xenikaki; Nicholas Alexandrou

Book ID
104221194
Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
112 KB
Volume
23
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Oxldatlon of the title compounds (1) with lead tetraacetate at rnnm temperature leads to the formatlon of 9,10-bls-arylazo-decalJnes (2) via a transannular reactlon, as well as to

๐Ÿ“œ SIMILAR VOLUMES

Study on the Transannular Lead Tetraacet
Study on the Transannular Lead Tetraacetate Oxidation of Some Medium-sized Ring Diketone Bis(arylhydrazones)
โœ Malamidou-Xenikaki, Elizabeth ;Alexandrou, Nicholas E. ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 426 KB

Oxidation of bis(ary1hydrazones) 1 ad of t,5-cyclooctanedione with lead tetraacetate mainly leads, via a transannular reaction, to the corresponding bicyclic bis(ary1azo) compounds 3a -d, whereas bis(ary1hydrazones) 2a -d of 3,8-cyclodecadiene-l,6-dione under the same conditions mainly give monocycl