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Transacetalization with Acylium Ions. A Structurally Diagnostic Ion/Molecule Reaction for Cyclic Acetals and Ketals in the Gas Phase

✍ Scribed by Moraes, Luiz Alberto B.; Gozzo, Fábio C.; Eberlin, Marcos N.; Vainiotalo, Pirjo


Book ID
126023261
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
208 KB
Volume
62
Category
Article
ISSN
0022-3263

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✍ Eduardo C. Meurer; Regina Sparrapan; Marcos N. Eberlin 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 135 KB 👁 1 views

## Abstract The intrinsic reactivity of eight gaseous, mass‐selected 2‐azabutadienyl cations toward polar [4^+^ + 2] cycloaddition with ethyl vinyl ether has been investigated by pentaquadrupole mass spectrometric experiments. Cycloaddition occurs readily for all the ions and, with the only excepti