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trans-Pentacarbonylrhenio(phenylcarbyne)tetracarbonylmolybdenum: A Transition Metal Carbyne Complex Containing a Metal-Metal Bond

✍ Scribed by Prof. Dr. Ernst Otto Fischer; Doz. Dr. Gottfried Huttner; Dipl.-Chem. Tassilo Lothar Lindner; Dipl.-Chem. Albin Frank; Dr. Fritz Roland Kreissl


Publisher
John Wiley and Sons
Year
1976
Tongue
English
Weight
159 KB
Volume
15
Category
Article
ISSN
0044-8249

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Carbonylation of Transition-Metal Carbyn
✍ Dr. Fritz R. Reissl; Dipl.-Chem. Wolfgang Uedelhoven; Dipl.-Chem. Karl Eberl πŸ“‚ Article πŸ“… 1978 πŸ› John Wiley and Sons 🌐 English βš– 141 KB πŸ‘ 2 views

**Surprising reactions of carbon monoxide with transition metal complexes** have been observed with compounds __(1)__ and __(2)__. The carbyne complex __(1)__ takes up CO at normal pressure and βˆ’30Β°C to form the metalated ketene __(2)__ which itself is deoxygenated by CO at +60Β°C and under 60atm pre