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trans-Hydroalumination/Alkylation: One-Pot Synthesis of Trisubstituted Allylic Alcohols.

✍ Scribed by Neil F. Langille; Timothy F. Jamison

Publisher
John Wiley and Sons
Year
2006
Weight
38 KB
Volume
37
Category
Article
ISSN
0931-7597

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One-Pot Synthesis of Trisubstituted 1,2-
One-Pot Synthesis of Trisubstituted 1,2-Amino Alcohols from Deprotonated Ξ±-Amino Nitriles
✍ Coralie Kison; Till Opatz πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 159 KB

## Abstract A short synthesis of __N__,1,2‐trisubstituted vicinal amino alcohols by 1,2‐addition of deprotonated __N__‐monosubstituted α‐amino nitriles to aldehydes and subsequent one‐pot reduction of the intermediates with borane–THF is described. This procedure leads to the predominant formation