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Trans-cis photoisomerization of 3-styryl-2',4',6'-triisopropylstilbene. Steric effects on location of the electronic excitation

✍ Scribed by Ito, Yoshikatsu.; Dote, Toshimichi.; Uozu, Yoshihiro.; Matsuura, Teruo.


Book ID
126023044
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
278 KB
Volume
108
Category
Article
ISSN
0002-7863

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trans–cis Photoisomerization of the Styr
✍ Julien Bossert; Chantal Daniel 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 274 KB 👁 1 views

## Abstract The __trans‐cis__ isomerization of the styrylpyridine carbon–carbon double bond induced by visible light irradiation in __fac__‐[Re(CO)~3~(bpy)(stpy)]^+^ (bp__y__ = 2,2′‐bipyridine; stpy = __t__‐4‐styrylpyridine) has been investigated by means of quantum‐chemical methods. The structures