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trans-Bis[acetone (2-oxidobenzo­yl)hydrazonato-κ2N,O]diaqua­zinc(II)

✍ Scribed by Li, Ming-Xue ;Zhou, Jing ;Yan, Lin ;Wang, Jing-Ping

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
251 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Zn(C 10 H 11 N 2 O 2 ) 2 (H 2 O) 2 ], the Zn II atom lies on an inversion centre, and is coordinated in a distorted octahedral geometry by two carbonyl O atoms and two imine N atoms from two anionic bidentate acetone (2oxidobenzoyl)hydrazone ligands and two aqua ligands. The complexes are linked together via O-HÁ Á ÁO hydrogen bonds, leading to a two-dimensional network.

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Single-crystal X-ray study T = 291 K Mean (C-C) = 0.003 A R factor = 0.025 wR factor = 0.069 Data-to-parameter ratio = 16.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.