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Trans-1-butadienyltriphenylphosphonium bromide: A reagent for the 1,3-cyclohexadienylation of carbonyl groups.

✍ Scribed by P.L. Fuchs


Book ID
104243202
Publisher
Elsevier Science
Year
1974
Tongue
French
Weight
182 KB
Volume
15
Category
Article
ISSN
0040-4039

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A variety of 1,3-oxathiolanes undergo a benzyne-induced fragmentation leading to phenyl vinyl sulfides and carbonyl compounds. The reaction developed here provides a novel method for deprotection of carbonyl compounds from 1,3-oxathiolanes, preparation of phenyl vinyl sulfides, and 1,2-carbonyl tran