## Abstract The spontaneous hydrolysis of phenyl chloroformate was studied in various anionic, nonionic, zwitterionic, and cationic aqueous micellar solutions, as well as in mixed anionicβnonionic micellar solutions. In all cases, an increase in the surfactant concentration results in a decrease in
β¦ LIBER β¦
Tracer diffusion of zwitterionic and ionic mixed micelles. Effect of micellar size and charge
β Scribed by Toshihiro Tominaga; Tomoyo Nakamura
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 282 KB
- Volume
- 73-74
- Category
- Article
- ISSN
- 0167-7322
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β¦ Synopsis
Difision
coefficients of pyrene solubilized in mixed micelles of 3-(N-tetradecyl-N,Ndimethylammonio)propanesulfonate (C&APS) and sodium octadecanesulfonate (CrsSOjNa) or sodium decanesulfonate (CroSOaNa) have been measured in aqueous NaBr solutions at 298.2 K. The diffusion coefftcients decrease with increasing molar ratio of CuSOxNa or CroSOsNa to C&APS.
The diffusion coefficients for the mixed micelles are lower in water than in salt solutions.
The results are interpreted in terms of the size and charge of the mixed micelles.
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