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Towards Syntheses and Structures of Heterometallic Clusters Containing Tantalum-tetrachalcogenato Building Blocks

✍ Scribed by Dieter Fenske; Ibrahim Issac; Alexander Rothenberger


Publisher
Springer
Year
2007
Tongue
English
Weight
310 KB
Volume
18
Category
Article
ISSN
1040-7278

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Alkylation of the SCS linkage. Towards l
✍ Jilles J. H. Edema; Marcel Hoogenraad; Franck S. Schoonbeek; Richard M. Kellogg; 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 594 KB

## Abstract Reaction of 1,3,5‐trithiane with BuLi in THF at ‐ 50°C, followed by reaction with an equivalent amount of alkyl halide [__n__‐hexyl (a), benzyl (b), __n__‐dodecyl (c)] affords the corresponding lipophilic alkyl trithianes in moderate to good yields (25‐75%). Reactions with xylylene dibr