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Towards near-IR emissive rhenium tricarbonyl complexes: Synthesis and characterisation of unusual 2,2′-biquinoline complexes

✍ Scribed by Andrew J. Hallett; Simon J.A. Pope

Book ID: 113661819
Publisher: Elsevier Science
Year: 2011
Tongue: English
Weight: 368 KB
Volume: 14
Category: Article
ISSN: 1387-7003
DOI: 10.1016/j.inoche.2011.06.021

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## Abstract A series of new rhenium(I) complexes of the type [Re^I^(CO)~3~(L)(L′)]^__n__+^ (L = 2,2′‐biquinoline (bqui) or 3,3′‐(ethane‐1,2‐diyl)‐2,2′‐biquinoline (CH~2~CN~2~)bqui); L′ = CF~3~SO$\rm{\_3^ - }$, pyridine (py), or 4‐substituted pyridine (HOpy, Bzpy, or NCpy); __n__ = 0 or 1) were prep