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Toward (Z)-selective Horner–Wadsworth–Emmons reaction of aldehydes with 2-fluoro-2-diethylphosphonoacetic acid

✍ Scribed by Shigeki Sano; Rie Teranishi; Yoshimitsu Nagao

Book ID: 104252426
Publisher: Elsevier Science
Year: 2002
Tongue: French
Weight: 113 KB
Volume: 43
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(02)02269-4

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✦ Synopsis

The stereoselective Horner-Wadsworth-Emmons reaction of aldehydes with 2-fluoro-2-diethylphosphonoacetic acid utilizing i-PrMgBr afforded (Z)-a-fluoro-a,b-unsaturated carboxylic acids as the major products.

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