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Toward the Development of a General Chiral Auxiliary. Enantioselective Alkylation and a New Catalytic Asymmetric Addition of Silyloxyfurans: Application to a Total Synthesis of (−)-Rasfonin

✍ Scribed by Boeckman,, Robert K.; Pero, Joseph E.; Boehmler, Debra J.


Book ID
111645475
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
59 KB
Volume
128
Category
Article
ISSN
0002-7863

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Synthesis of chiral dendrimers with a hy
✍ Itaru Sato; Takanori Shibata; Koji Ohtake; Ryo Kodaka; Yutaka Hirokawa; Nobuaki 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 137 KB

Chiral dendrimers with three or six β-amino alcohols on hyperbranched hydrocarbon chain-ends were synthesized. These macromolecules can act as chiral catalysts for the enantioselective addition of dialkylzincs to aldehydes. The corresponding secondary alcohols are obtained in high enantiomeric exces