Toward Living Radical Polymerization
β Scribed by Rizzardo, Ezio; Thang, San H.; Moad, Graeme
- Book ID
- 111871156
- Publisher
- American Chemical Society
- Year
- 2008
- Tongue
- English
- Weight
- 619 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0001-4842
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π SIMILAR VOLUMES
This review covers fundamental kinetic features of living radical polymerization (LRP). Theories on polymerization rate R p and polydispersity index (PDI) and experimental investigations into individual LRP systems are summarized. The presence of bimolecular termination, which is unavoidable in LRP
&&Living'' free-radical polymerization (LFRP) of styrene is usually performed following two di!erent reaction procedures: by TEMPO-mediated LFRP or by atom transfer radical polymerization. The main di!erence between the previous two processes is related to how the exchange between the active and the