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Toward an Understanding of the Unexpected Regioselective Hetero-Diels−Alder Reactions of Asymmetric Tetrazines with Electron-Rich Ethylenes: A DFT Study †

✍ Scribed by Domingo, Luis R.; Picher, M. Teresa; Sáez, José A.


Book ID
121809162
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
887 KB
Volume
74
Category
Article
ISSN
0022-3263

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✍ Luis R. Domingo; M. Teresa Picher; Pau Arroyo 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 212 KB 👁 1 views

## Abstract The polar Diels–Alder reactions of nitrosoalkenes with enamines have been studied using DFT methods at the B3LYP/6‐31G\* level of theory. These Diels–Alder reactions are characterized by a nucleophilic attack of the enamine at the conjugated position of the nitrosoalkene with concomitan