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Toward an Understanding of the Mechanism of Metal Exchange in (Propargyl Alcohol)Co 2 (CO) 6 Clusters: Syntheses and Structures of [η 5 -C 5 Ph 2 R 2 −C⋮C−TMS)(Fe(CO) 2 (μ-H)]Co 2 (CO) 6 , R = Ph or Et

✍ Scribed by Dunn, James A.; Britten, James F.; Daran, Jean-Claude; McGlinchey, Michael J.


Book ID
120492928
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
94 KB
Volume
20
Category
Article
ISSN
0276-7333

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Reactivity of the Inversely Polarised Ar
✍ Lothar Weber; Philipp Bayer; Gabriel Noveski; Hans-Georg Stammler; Beate Neumann 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 177 KB

## Abstract The reaction of the vinylidene complexes [(C~5~H~5~)(CO)(NO)W=C=C(H)R] (10a: R = __t__Bu; 10b: R = Ph) with the arsaalkene __t__BuC(O)–As=C(NMe~2~)~2~ (11) afforded the novel η^2^‐1‐arsaallene complexes [η^2^‐{__t__BuC(O)–As=C=C(H)R}W(CO)(NO)C~5~H~5~] (13: R = __t__Bu; 15: R = Ph). Simi