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Total synthesis of verrucarol

โœ Scribed by Trost, Barry M.; McDougal, Patrick G.

Book ID
125990454
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
421 KB
Volume
104
Category
Article
ISSN
0002-7863

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Total synthesis of (-)-verruearol (1) was achieved starling from D-glucose-derived bicyclic lactone 4 through l) a stereoselective asymmetric quatemization of the a-carbon of the lactone, 2) Dieckmann cyclization for access to the C-ring equivalent, 3) a skeletal rearrangement for the trichothecene