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Total Synthesis of (-)-Ulapualide A (I): The Danger of Overdependence on NMR Spectroscopy in Assignment of Stereochemistry.

✍ Scribed by Gerald Pattenden; Neil J. Ashweek; Charles A. G. Baker-Glenn; Gary M. Walker; James G. K. Yee


Publisher
John Wiley and Sons
Year
2007
Weight
16 KB
Volume
38
Category
Article
ISSN
0931-7597

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Spiroxamine is a new powdery mildew fungicide in cereals consisting of four biologically active isomers (two diastereomers, four enantiomers). The four isomers were separated by preparative high-performance liquid chromatography (HPLC) on a chiral stationary phase. At this stage it was not possible