๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Total synthesis of the putative structure of the novel triquinane natural product isocapnellenone

โœ Scribed by Goverdhan Mehta; A.Sai Krishna Murthy; Jayant D. Umarye

Book ID
104252198
Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
209 KB
Volume
43
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

โœฆ Synopsis

A total synthesis of the 'putative structure' 7, attributed to the novel triquinane sesquiterpene isolated recently from two Buddelia species has been accomplished. The spectral data for 7 is a complete mismatch with those reported for the natural product and warrants a revision of the assigned structure.

๐Ÿ“œ SIMILAR VOLUMES

A stereoselective total synthesis of the
A stereoselective total synthesis of the novel triquinane sesquiterpene cucumin E
โœ Goverdhan Mehta; Jayant D Umarye ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 69 KB

A total synthesis of cucumin E, a recently isolated triquinane natural product with a new carbon framework, has been achieved. The key step is the flash vacuum pyrolysis (FVP)-induced cyclobutane fragmentation in a readily available pentacyclic caged dione to deliver the triquinane skeleton with fun