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Total Synthesis of the Proposed Structure of the Anthrapyran Metabolite δ-Indomycinone

✍ Scribed by Lutz F. Tietze; Ramakrishna Reddy Singidi; Kersten M. Gericke

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
330 KB
Volume
13
Category
Article
ISSN
0947-6539

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✍ Thomas G. Minehan; Yoshito Kishi 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 91 KB 👁 1 views

Four monocyclic precursors were assembled in the total synthesis of the proposed structure 1-A of (+)-tolyporphin A O,O-diacetate (X=Ac). Comparison of the spectroscopic data demonstrated that synthetic tolyporphin O,O-diacetate did not match the O,O-diacetate prepared from natural (+)-tolyporphin A