Total Synthesis of the Coccinellid Alkaloid (.+-.)-Adalinine Utilizing a Nitrenium Ion Cyclization.
β Scribed by Duncan J. Wardrop; Chad L. Landrie; Jose A. Ortiz
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 72 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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Studies Toward the Total Synthesis of the Oxindole Alkaloid Gelsedine: An Efficient Allene-Terminated N-Acyliminium Ion Cyclization. -The preparation of the advanced synthetic intermediate (VII) in the projected synthesis of enantiopure ent-gelsedine is reported. The use of the inexpensive (S)-enan