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Total synthesis of the antiinflammatory and proresolving protectin D1

✍ Scribed by Narihito Ogawa; Yuichi Kobayashi

Publisher: Elsevier Science
Year: 2011
Tongue: French
Weight: 580 KB
Volume: 52
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2011.03.152

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✦ Synopsis

Stereoselective total synthesis of protectin D1 was completed through construction of the Z,E,E-triene structure by using the Suzuki coupling between the vinyl borane (C13-C22) and the vinyl iodide (C1-C12). The Z-enyne, the acetylene precursor of the vinyl borane was synthesized from optically active

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