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Total Synthesis of Seco (+)- and ent -(−)-Oxaduocarmycin SA: Construction of the (Chloromethyl)indoline Alkylating Subunit by a Novel Intramolecular Aryl Radical Cyclization onto a Vinyl Chloride

✍ Scribed by Patel, Vinod F.; Andis, Sherri L.; Enkema, Julia K.; Johnson, David A.; Kennedy, Joseph H.; Mohamadi, Fariborz; Schultz, Richard M.; Soose, Daniel J.; Spees, Michael M.

Book ID
125488908
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
264 KB
Volume
62
Category
Article
ISSN
0022-3263

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ChemInform Abstract: Total Synthesis of
ChemInform Abstract: Total Synthesis of seco-(+)- and ent-(-)-Oxaduocarmycin SA: Construction of the (Chloromethyl)indoline Alkylating Subunit by a Novel Intramolecular Aryl Radical Cyclization onto a Vinyl Chloride.
✍ V. F. PATEL; S. L. ANDIS; J. K. ENKEMA; D. A. JOHNSON; J. H. KENNEDY; F. MOHAMAD 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 39 KB 👁 2 views

Total Synthesis of seco-(+)-and ent-(-)-Oxaduocarmycin SA: Construction of the (Chloromethyl)indoline Alkylating Subunit by a Novel Intramolecular Aryl Radical Cyclization onto a Vinyl Chloride. -The seco-(+) title compound (IX) is an analogue of the highly cytotoxic natural product duocarmycin SA,