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Total Synthesis of Neplanocin A

✍ Scribed by Michael Jung; Gustav Offenbächer; János Rétey

Publisher
John Wiley and Sons
Year
1983
Tongue
German
Weight
459 KB
Volume
66
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

The first total synthesis of racemic neplanocin A **(1)**After submitting our paper we learned that Arita et al. [J. Am. Chem. Soc.105, 4049(1983)] synthesized the natural enantioner of Neplanocin A.

from cyclopentadiene and acylnitroso‐3,5‐dinitrobenzoic acid is described. The synthesis is suitable for specific isotopic labelling of the hydroxymethyl group of neplanocin A.

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