Total Synthesis of Murrayanine Involving
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Pablo Bernal; JoaquΓn Tamariz
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Article
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2007
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John Wiley and Sons
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German
β 80 KB
## Abstract A new total synthesis of the natural carbazole murrayanine (**1**) was developed by using the 4,5βdimethyleneoxazolidinβ2βone **12** as starting material. The latter underwent a highly regioselective __DielsβAlder__ cycloaddition with acrylaldehyde (=propβ2βenal; **13**) to give adduct