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Total Synthesis of (+)-Lysergic Acid

✍ Scribed by Liu, Qiang; Jia, Yanxing

Book ID
115458913
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
799 KB
Volume
13
Category
Article
ISSN
1523-7060

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πŸ“œ SIMILAR VOLUMES

Total Synthesis of (+)-Lysergic Acid
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Total Synthesis of Lysergic Acid
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THE TOTAL SYNTHESIS OF LYSERGIC ACID AND
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## Abstract (Β±)‐Lysergic acid (**1**) has been synthesized from 4‐hydroxymethyl‐1‐tosylindole (**2**) by a sequence of 9 steps. The crucial thermolysis **9** β†’ **10** involves the __in situ__‐generation of the transient diene III which undergoes an intramolecular cycloaddition to a C, N‐double bond