Palladium(O)-catalyzed coupling of cyclopropylzinc halides, readily prepared from the corresponding cyclopropyl(tri-D-butyl)stannanes, with vinyl iodides provides good yields of functionalized vinylcyclopropanes. The coupling reaction is used as a key step in total syntheses of the sesquiterpenoids
โฆ LIBER โฆ
Total synthesis of linear polyprenoids. 3. Syntheses of ubiquinones via palladium-catalyzed oligomerization of monoterpene monomers
โ Scribed by Eren, Doron.; Keinan, Ehud.
- Book ID
- 127330842
- Publisher
- American Chemical Society
- Year
- 1988
- Tongue
- English
- Weight
- 951 KB
- Volume
- 110
- Category
- Article
- ISSN
- 0002-7863
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The Palladium-Catalyzed Enyne Cycloisomerization Reaction in a General Approach to the Asymmetric Syntheses of the Picrotoxane Sesquiterpenes. Part 1. First-Generation Total Synthesis of Corianin (V) and Formal Syntheses of Picrotoxinin (VIa) and Picrotin (VIb).