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Total synthesis of (+)-Leukotriene B4 methyl ester and its 5-epimer from (R)-glycidol

✍ Scribed by M. Avignon-Tropis; M. Treilhou; J.R. Pougny; I. Fréchard-Ortuno; G. Linstrumelle

Publisher: Elsevier Science
Year: 1991
Tongue: French
Weight: 560 KB
Volume: 47
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(01)89730-1

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✦ Synopsis

The Pd-Cu coupling reaction of a chrral hydroxy-(E,E)-rododrene wrth a racemlc acetylenlc alcohol followed by reduction of the dlenyne leads to the desired (Z.E,E) geometry and allows synthesis of LTB4 and its S-eprmer after reparation of dlastereomers

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