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Total synthesis of ionophores. 6. Asymmetric induction in the permanganate-promoted oxidative cyclization of 1,5-dienes

โœ Scribed by Walba, David M.; Przybyla, Claire A.; Walker, Christopher B.

Book ID
121326122
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
293 KB
Volume
112
Category
Article
ISSN
0002-7863

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โœ David J. Morgans Jr. ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 236 KB

## Cyclic hydroboration of an appropriately substituted 1.5~diene yields a 1,5 dial as the major product which can be converted to the racemic Prelog-Djerassi lactone. The widespread occurrence of the three carbon unit 1 in natural products of current synthetic interest has prompted us to investig