The novel tetracyclic sesquiterpenoid (+)-cyclomyltaylan-5o~ol 1 has been synthesized starting from (S)-(+)-Hajos-Wiechert ketone analogue 3 via SmI2-promoted reductive cyclization as a key step. Thus, the absolute configuration has been established to be 2R,3R, 4R,5S,6R,7R (cyclomyltaylane numberin
โฆ LIBER โฆ
Total synthesis of herbertenediol, an isocuparane sesquiterpene isolated from liverworts
โ Scribed by Yoshiyasu Fukuyama; Yuuko Kiriyama; Mitsuaki Kodama
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- French
- Weight
- 156 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0040-4039
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