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Total synthesis of (−)-halosaline by a ruthenium-catalyzed ring rearrangement

✍ Scribed by Roland Stragies; Siegfried Blechert

Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
657 KB
Volume
55
Category
Article
ISSN
0040-4020

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✦ Synopsis

The stereoselective synthesis of substituted piperidines by a rutheniumcatalyzed ring rearrangement of cyclopentene derivatives is demonstrated. The influence of different substituents and the effect of ethylene on the metathesis reaction is described. The ring rearrangement can be combined with a molybdenum-catalyzed cross metathesis reaction using allyltrimethyl silane as coupling partner. The first total synthesis of (-)-halosaline was accomplished via domino metathesis reaction utilizing Grubbs' ruthenium catalyst.

📜 SIMILAR VOLUMES

ChemInform Abstract: Total Synthesis of
ChemInform Abstract: Total Synthesis of (-)-Halosaline by a Ruthenium-Catalyzed Ring Rearrangement.
✍ Roland Stragies; Siegfried Blechert 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

ChemInform Abstract: Variable and Stereo
ChemInform Abstract: Variable and Stereoselective Synthesis of Azasugar Analogues by a Ruthenium-Catalyzed Ring Rearrangement.
✍ Ulrike Voigtmann; Siegfried Blechert 📂 Article 📅 2001 🏛 John Wiley and Sons ⚖ 32 KB 👁 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v