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Total synthesis of (±)-fukinone

✍ Scribed by A.K. Torrence; A.R. Pinder


Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
142 KB
Volume
12
Category
Article
ISSN
0040-4039

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✦ Synopsis


received in UK for publication 16 Febnzary 191) (+I-Fukinone is a bicyclic ketone isolated recently from flower stems of Petasites japonicus Maxim. A study of its chemical and spectral properties culminated in the structure and absolute stereochemistry depicted in & 1

The ketone is a member of the ever-increasing family of sesquiterpenes derived from eremophilane. 2

We describe here a stereospecific total variety of fukinone (1). 2,3_Dimethylphenol


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