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Total synthesis of (.+-.)-eriolanin

✍ Scribed by Grieco, Paul A.; Oguri, Tomei; Gilman, S.; DeTitta, George T.

Book ID: 126286110
Publisher: American Chemical Society
Year: 1978
Tongue: English
Weight: 364 KB
Volume: 100
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00473a056

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## Abstract Using a sultone as the key intermediate, the first enantioselective total synthesis of the antileukemic 1,10‐__seco__‐eudesmanolides (–)‐eriolanin (**1**) and (–)‐eriolangin (**2**) was achieved, which also established the hitherto unknown absolute configuration of these sesquiterpene l